Chemical Science · 2018 · 56 citations · 52 references
Natural SciencesChemistryCatalysisOrganic ChemistryHeterocycle SynthesisHeterocyclic ChemistryHeterocyclic CompoundsMetal CatalysisMetal Ion CatalysisOrganic SynthesisAsymmetric Heterocycle SynthesisCopper CatalysisCopper-catalyzed CouplingCyclopropanation ReactionsHydride FormationMetal-mediated Cyclization
A highly diastereo- and enantioselective protocol for the hydroallylation of 1,1- and 1,2-disubstituted cyclopropenes has been developed utilizing an <italic>in situ</italic> formed copper hydride.
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