Concepedia

Synthesis of Chloro(phenyl)trifluoromethyliodane and Catalyst-Free Electrophilic Trifluoromethylations

Cong Xu, Xiaoning Song, Jia Guo, Sibao Chen, Jie Gao, Jing Jiang, Fengyun Gao, Yuxin Li, Mang Wang

Organic Letters · 2018 · 77 citations · 47 references

DOI

Concepts

Abstract

-transfer capability in electrophilic S-, O-, N-, and C-trifluoromethylations as well as in catalyst-free trifluoromethylation-cyclizations of arylisonitriles.

References

47

Novel 10‐I‐3 Hypervalent Iodine‐Based Compounds for Electrophilic Trifluoromethylation

Patrick Eisenberger, S. Gischig, Antonio Togni · Chemistry - A European Journal · 2006 · 600 citations

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Strategies for nucleophilic, electrophilic, and radical trifluoromethylations

Jun‐An Ma, Dominique Cahard · Journal of Fluorine Chemistry · 2007 · 560 citations

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Power-variable electrophilic trifluoromethylating agents. S-, Se-, and Te-(trifluoromethyl)dibenzothio-, -seleno-, and -tellurophenium salt system

Teruo Umemoto, Sumi Ishihara · Journal of the American Chemical Society · 1993 · 539 citations

, , +5

Mild Electrophilic Trifluoromethylation of Carbon‐ and Sulfur‐Centered Nucleophiles by a Hypervalent Iodine(III)–CF<sub>3</sub> Reagent

Iris Kieltsch, Patrick Eisenberger, Antonio Togni · Angewandte Chemie International Edition · 2006 · 520 citations

, , +9

Nucleophilic Trifluoromethylation Reactions of Organic Compounds with (Trifluoromethyl)trimethylsilane

Rajendra Prasad Singh, Jean’ne M. Shreeve · Tetrahedron · 2000 · 406 citations

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