Role of a 2,3-bis(pyridyl)pyrazinyl chelate bridging ligand in the reactivity of Ru(<scp>ii</scp>)–Pt(<scp>ii</scp>) dinuclear complexes on the substitution of chlorides by thiourea nucleophiles – a kinetic study

Abstract

Effect of a bridged ligand on the chloride substitution from hetero bimetallic Ru(<sc>ii</sc>)–Pt(<sc>ii</sc>)dichlo complexes by thiourea nucleolus was studied in a methanol medium (<italic>I</italic>= 0.10 M) under pseudo-first-order conditions.