Chemical complexity induced local structural distortion in NiCoFeMnCr high-entropy alloy

Fuxiang Zhang, Yang Tong, Ke Jin, Hongbin Bei, William J. Weber, Ashfia Huq, Antonio Lanzirotti, M. Newville, Darren C. Pagan, Jun Yeong Ko,

Materials Research Letters · 2018 · 76 citations · 26 references

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Abstract

In order to study chemical complexity-induced lattice distortion in high-entropy alloys, the static Debye–Waller (D-W) factor of NiCoFeMnCr solid solution alloy is measured with low temperature neutron diffraction, ambient X-ray diffraction, and total scattering methods. The static atomic displacement parameter of the multi-element component alloy at 0 K is 0.035–0.041 Å, which is obvious larger than that of element Ni (∼ 0 Å). The atomic pair distance between individual atoms in the alloy investigated with extended X-ray absorption fine structure (EXAFS) measurements indicates that Mn has a slightly larger bond distance (∼0.4%) with neighbor atoms than that of others.

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