Concepedia

Hydrogen evolution catalysis by molybdenum sulfides (MoS<sub>x</sub>): are thiomolybdate clusters like [Mo<sub>3</sub>S<sub>13</sub>]<sup>2−</sup> suitable active site models?

Marie‐Luise Grutza, Ashwene Rajagopal, Carsten Streb, Philipp Kurz

Sustainable Energy & Fuels · 2018 · 70 citations · 70 references

DOI

Concepts

Abstract

Recent results concerning molecular molybdenum sulfido clusters as model systems for heterogeneous hydrogen evolution catalysis by molybdenum sulfides are summarized and also compared to the related chemistry of the active site of the enzyme Mo-nitrogenase.

References

70

MoS<sub>2</sub> Nanoparticles Grown on Graphene: An Advanced Catalyst for the Hydrogen Evolution Reaction

Yanguang Li, Hailiang Wang, Liming Xie et al. · Journal of the American Chemical Society · 2011 · 5K citations

, , +17

Biomimetic Hydrogen Evolution:  MoS<sub>2</sub>Nanoparticles as Catalyst for Hydrogen Evolution

Berit Hinnemann, Poul Georg Moses, Jacob Bonde et al. · Journal of the American Chemical Society · 2005 · 4K citations

, , +17

Polyoxometalate Chemistry: An Old Field with New Dimensions in Several Disciplines

Michael T. Pope, Achim Müller · Angewandte Chemie International Edition in English · 1991 · 3.6K citations

, , +16

Stretching and Breaking of Ultrathin MoS<sub>2</sub>

Simone Bertolazzi, Jacopo Brivio, András Kis · ACS Nano · 2011 · 2.6K citations · Full text

, , +17

Catalyzing the Hydrogen Evolution Reaction (HER) with Molybdenum Sulfide Nanomaterials

Jesse D. Benck, Thomas R. Hellstern, Jakob Kibsgaard et al. · ACS Catalysis · 2014 · 1.6K citations

, , +17