Angewandte Chemie International Edition · 2018 · 59 citations · 28 references
Natural SciencesChemistryMaterials ScienceCrystal StructureMaterials ChemistrySurface ChemistryCrystal ChemistryCrystal EngineeringCrystal SystemsCrystalline MaterialsPorous MaterialsSupramolecular MaterialsHydrophobicityMolecular CrystalsOrganic CrystalsPhysical PropertiesPorous CrystalsSurface Hydrophobicity EffectsSurface Hydrophobicity Tuning
Abstract The first examples of core–shell porous molecular crystals are described. The physical properties of the core–shell crystals, such as surface hydrophobicity, CO 2 /CH 4 selectivity, are controlled by the chemical composition of the shell. This shows that porous core–shell molecular crystals can exhibit synergistic properties that out‐perform materials built from the individual, constituent molecules.
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