<i>cis</i>-Cyclodiphosph(<scp>v</scp>/<scp>v</scp>)azanes as highly stable and robust main group supramolecular building blocks

Abstract

Bench-top stable <italic>cis</italic>-cyclodiphosph(<sc>v</sc>/<sc>v</sc>)azanes are demonstrated to form robust R21(8) bifurcated hydrogen-bonds and PSe⋯Br halogen bonds. This work highlights the potential of cyclodiphosph(<sc>v</sc>/<sc>v</sc>)azane building blocks in creating new supramolecular assemblies.