Carbon‐Encapsulated WO<i>_x</i> Hybrids as Efficient Catalysts for Hydrogen Evolution

Abstract

Abstract Developing non‐noble metal catalysts as Pt substitutes, with good activity and stability, remains a great challenge for cost‐effective electrochemical evolution of hydrogen. Herein, carbon‐encapsulated WO x anchored on a carbon support (WO x @C/C) that has remarkable Pt‐like catalytic behavior for the hydrogen evolution reaction (HER) is reported. Theoretical calculations reveal that carbon encapsulation improves the conductivity, acting as an electron acceptor/donor, and also modifies the Gibbs free energy of H* values for different adsorption sites (carbon atoms over the W atom, O atom, WO bond, and hollow sites). Experimental results confirm that WO x @C/C obtained at 900 °C with 40 wt% metal loading has excellent HER activity regarding its Tafel slope and overpotential at 10 and 60 mA cm −2 , and also has outstanding stability at −50 mV for 18 h. Overall, the results and facile synthesis method offer an exciting avenue for the design of cost‐effective catalysts for scalable hydrogen generation.