Concepedia

Revealing the unusual role of bases in activation/deactivation of catalytic systems: O–NHC coupling in M/NHC catalysis

Victor M. Chernyshev, Oleg V. Khazipov, Andrey Yu. Chernenko, Alexander V. Astakhov, Dmitry B. Eremin, Dmitry V. Pasyukov, Alexey S. Kashin, Valentine P. Ananikov

Chemical Science · 2018 · 80 citations · 61 references

DOIFull text

Open access

Concepts

Abstract

Usual oxygen bases decompose M/NHC complexes to give “NHC-free” metal species and azolones.

References

61

An overview of N-heterocyclic carbenes

Matthew N. Hopkinson, Christian Richter, Michael Schedler et al. · Nature · 2014 · 4.2K citations

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N-Heterocyclic Carbenes: A New Concept in Organometallic Catalysis

Wolfgang A. Herrmann · Angewandte Chemie International Edition · 2002 · 3.8K citations

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Palladium‐Catalyzed Cross‐Coupling Reactions in Total Synthesis

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Recent applications of the Suzuki–Miyaura cross-coupling reaction in organic synthesis

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Recent Applications of Palladium‐Catalyzed Coupling Reactions in the Pharmaceutical, Agrochemical, and Fine Chemical Industries

C. Torborg, Matthias Beller · Advanced Synthesis & Catalysis · 2009 · 1.5K citations

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