Proof of concept for an optogalvanic gas sensor for NO based on Rydberg excitations

Abstract

We demonstrate the applicability of 2-photon Rydberg excitations of nitric oxide (NO) at room temperature in a gas mixture with helium (He) as an optogalvanic gas sensor. The charges created initially from preceding collisions of excited NO Rydberg molecules with free electrons are measured as a current on metallic electrodes inside a glass cell and amplified using a custom-designed high-bandwidth transimpedance amplifier attached to the cell. We find that this gas sensing method is capable of detecting NO concentrations lower than 10 ppm even at atmospheric pressures, currently only limited by the way we prepare gas dilutions.