Effect of Zn on the structural and electrical properties of high temperature HgBa2Ca2Cu3O8+δ superconductor

Abstract

Bulk polycrystalline HgBa2Ca2-yZnyCu3O8+δ compound samples with y =0.0, 0.05, 0.1, 0.15, 0.2, 0.25, and 0.3, are synthesized by a solid state reaction process. Study identifies Zinc partial substitution on superconductivity behavior. Structural properties are studied by using X-ray powder pattern, the high temperature phase superconductor (Hg-1223) of the tetragonal structure didn’t change with the partial substitution of Zn ions in Ca site, lattice parameters c, c/a are established to vary Zn-substitution. The surface morphology has been studied by using atomic force microscopes (AFM), showed that all specimens have good crystalline and homogeneous surface. Also give a best nano size value is 83.29 nm at y=0.05. Four probe technique is used to measure Tc. The highest Tc and oxygen content were found to be Tc=132 K for y=0.05 after that, Tc decreases from 132 K to 115 K with increasing Zn. In addition, dielectric properties (dielectric constant, dielectric loss factor, and the alternating electrical conductivity) are characterized directly by relating with Zn concentration.