Thermal and Mechanical Behavior of New Transparent Thermoplastic Polyurethane Elastomers Derived from Cycloaliphatic Diisocyanate

Abstract

New transparent thermoplastic polyurethane elastomers (TPURs) with the hard-segment content of ≈50 mass % were synthesized by one-step melt polyaddition of 1,1'-methanediylbis(4-isocyanatocyclohexane), 2,2'-methylenebis[(4,1-phenylene)-methylenesulfanediyl]diethanol (diol E), 3-hydroxy-2-(hydroxymethyl)-2-methylpropanoic acid (DMPA), a poly(oxytetramethylene) diol of M ¯ n = 1000 g/mol (PTMO), or a poly(hexametylene carbonate) diol of M ¯ n = 860 g/mol (PHCD). Herein, I prepared TPURs in which 20, 40, and 60 mol % of diol E was replaced with DMPA, an ionic chain extender. The structure of polymers was examined by ATR-FTIR. Their thermal and mechanical behaviors were determined by means of thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), dynamic mechanical thermal analysis (DMTA), tensile tests, and Shore A/D hardness. Their optical properties are described. Generally, the addition of carboxyl groups to the polymer resulted in decreases in their thermal stability, transparency, and refractive indexes. Furthermore, the use of different soft segments revealed significant differences in both mechanical and thermal properties of the polymers obtained.