CrystEngComm · 2018 · 53 citations · 29 references
EngineeringChemical EngineeringChemistryHeat TransferMicrowave EngineeringReaction EngineeringMicrowave-assisted SynthesisNucleationNucleation ThermodynamicsRadio-frequency HeatingCoolingMicrowave-assisted CatalysisSecondary NucleationSecondary Nucleation EffectsSide Reactions
Rapid cooling and microwave heating substantially speed up temperature cycling-enhanced deracemization, while limiting the concomitant side reactions. During fast cooling, secondary nucleation is shown to enable deracemization.
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Asymmetric autocatalysis and amplification of enantiomeric excess of a chiral molecule
Kenso Soai, Takanori Shibata, Hiroshi Morioka et al. · Nature · 1995 · 1.1K citations
Chiral Symmetry Breaking in Sodium Chlorate Crystallization
Dilip Kondepudi, Rebecca J. Kaufman, Nolini Singh · Science · 1990 · 963 citations