Chemical Communications · 2018 · 195 citations · 26 references
Natural SciencesChemical EngineeringChemistryElectrochemical EngineeringElectrochemistryEnergy MaterialsBattery TechnologyElectrochemical CellsElectrochemical Energy StorageEnergy StorageRedox ChemistryRedox-active MaterialsBattery ChemistryBattery Power DensityBattery Redox ChemistryFlow BatteriesPower DensityRadical StabilityRedox Flow BatteriesViologen-based Materials
A high voltage (1.38 V) total organic aqueous redox flow battery is reported using 1,1'-bis[3-(trimethylammonio)propyl]-4,4'-bipyridinium tetrachloride ((NPr)2V) as an anolyte and 4-trimethylammonium-TEMPO chloride (NMe-TEMPO) as a catholyte. The exceptional radical stability of [(NPr)2V]+˙ enabled the flow battery in achieving 97.48% capacity retention for 500 cycles and a power density of 128.2 mW cm-2.
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A metal-free organic–inorganic aqueous flow battery
Brian Huskinson, Michael P. Marshak, Changwon Suh et al. · Nature · 2014 · 1.6K citations · Full text
Recent Progress in Redox Flow Battery Research and Development
Wei Wang, Qingtao Luo, Bin Li et al. · Advanced Functional Materials · 2012 · 1.5K citations
Kaixiang Lin, Qing Chen, Michael R. Gerhardt et al. · Science · 2015 · 1.1K citations · Full text