A Bis‐Triazacyclononane Tris‐Pyridyl N₉‐Azacryptand “Beer Can” Receptor for Complexation of Alkali Metal and Lead(II) Cations

Abstract

A new bis-triazacyclononane tris-pyridyl N₉ -azacryptand ligand is prepared via a convenient one-pot [2+3] condensation reaction between triazacyclononane and 2,6-bis(bromomethyl) pyridine in the presence of M₂ CO₃ (M=Li, Na, K). The proton, lithium, sodium, potassium and lead(II) complexes of the ligand are characterised in the solid state. Preliminary solution-phase competition experiments indicate that the cryptand ligand preferentially binds lead(II) in the presence of sodium, calcium, potassium and zinc cations in methanol solution.