Concepedia

Polymerization based on alternating insertion of an isocyanide and alkyne into palladium–carbon bonds

Yuki Kataoka, Naoya Kanbayashi, Taka‐aki Okamura, Kiyotaka Onitsuka

Polymer Chemistry · 2018 · 12 citations · 41 references

DOI

Concepts

Abstract

The first polymerization system based on the alternating insertion of an isocyanide and alkyne into palladium–carbon bonds has been developed.

References

41

Alternating copolymerization of carbon monoxide and olefins by single-site metal catalysis

Claudio Bianchini, Andrea Meli · Coordination Chemistry Reviews · 2002 · 340 citations

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High-Molecular-Weight Polyquinoxaline-Based Helically Chiral Phosphine (PQXphos) as Chirality-Switchable, Reusable, and Highly Enantioselective Monodentate Ligand in Catalytic Asymmetric Hydrosilylation of Styrenes

Takeshi Yamamoto, Tetsuya Yamada, Yuuya Nagata et al. · Journal of the American Chemical Society · 2010 · 263 citations

, , +13

Polymers with Main-Chain Chirality. Synthesis of Highly Isotactic, Optically Active Poly(4-tert-butylstyrene-alt-CO) Using Pd(II) Catalysts Based on C2-Symmetric Bisoxazoline Ligands

Maurice Brookhart, Mark Wagner, G.G.A. Balavoine et al. · Journal of the American Chemical Society · 1994 · 255 citations

, , +11

Highly Enantioselective Alternating Copolymerization of Propene with Carbon Monoxide Catalyzed by a Chiral Phosphine-Phosphite-Palladium(II) Complex

Kyoko Nozaki, Naomasa Sato, Hidemasa Takaya · Journal of the American Chemical Society · 1995 · 188 citations

, , +15

Palladium(II)-Catalyzed Isospecific Alternating Copolymerization of Aliphatic .alpha.-Olefins with Carbon Monoxide and Isospecific Alternating Isomerization Cooligomerization of a 1,2-Disubstituted Olefin with Carbon Monoxide. Synthesis of Novel, Optically Active, Isotactic 1,4- and 1,5-Polyketones

Zhaozhong Jiang, Ayusman Sen · Journal of the American Chemical Society · 1995 · 184 citations

, , +11