Publication | Closed Access
Eosin Y as a Direct Hydrogen‐Atom Transfer Photocatalyst for the Functionalization of C−H Bonds
419
Citations
33
References
2018
Year
Broad Substrate ScopeChemical EngineeringEosin YEngineeringPhotoredox ProcessPhotochemistrySynthetic PhotochemistryPhotocatalysisSingle-atom CatalystCatalysisC−h BondsChemistryHydrogenPhotoelectrocatalysisMolecular CatalysisPhotoelectrochemistryNative C-h Bonds
Eosin Y, a well-known economical alternative to metal catalysts in visible-light-driven single-electron transfer-based organic transformations, can behave as an effective direct hydrogen-atom transfer catalyst for C-H activation. Using the alkylation of C-H bonds with electron-deficient alkenes as a model study revealed an extremely broad substrate scope, enabling easy access to a variety of important synthons. This eosin Y-based photocatalytic hydrogen-atom transfer strategy is promising for diverse functionalization of a wide range of native C-H bonds in a green and sustainable manner.
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