Development of a Perchlorate Chemical Sensor Based on Magnetic Nanoparticles and Silicon Nitride Capacitive Transducer

Abstract

Abstract We report in this work the development of a novel capacitance electrochemical sensors based on silicon nitride substrate (Si 3 N 4 ) chemically modified with a structure of Cobalt phthalocyanine, C,C,C,C‐tetracarboxylic acid‐Polyacrylamide (Co(II)Pc‐PAA). This sensitive layer was tested with and without magnetic nanoparticles (MNP) for perchlorate ( ) detection. The developed chemical sensor with Si 3 N 4 /APTES‐MNP/Co(II)Pc‐PAA structure has shown a better performance when compared to the other structure based on Si 3 N 4 /Co(II)Pc‐PAA. Contact angle measurements (CAM) and atomic force microscopy (AFM) characterizations have been performed to characterize the functionalization of the chemical sensors surface. Under the optimized structure of the chemical sensor, electrochemical measurements were carried out using Mott‐Schottky analysis for detection within the large range of 10 −10 to 10 −4 M with a very low detection limit of 2×10 −10 M. The chemical sensor has demonstrated a high selectivity toward when compared to other interfering anions such as Cl − , SO 4 2− , and CO 3 2− . The present capacitive chemical sensor is very promising for sensitive and rapid detection of for environmental applications.