Removal of nitrophenols from water using cellulose derived nitrogen doped graphitic carbon material containing titanium dioxide

Abstract

Nitrophenols (NPs) and their derivatives are highly toxic, mutagenic and bio-refractory pollutants commonly present in natural water resources and industrial wastewater. To remove NPs from water, N-doped graphitic carbon (NGC) and NGC adsorbent containing titanium dioxide (NGC–TiO₂) were synthesized by pyrolysis of microcrystalline cellulose and dopamine mixture, and the mixture along with TiO₂ at 500°C, respectively. NCG-TiO₂ was thoroughly characterized using various analytical techniques. NP adsorption on the NGC–TiO₂ adsorbent surface was studied by varying the pH, initial concentration of NP, and adsorbent dose. The results showed that the most efficient adsorption was achieved at pH 3. After 4 h sonication at pH 3, 80% 4-NP adsorption was achieved using NGC–TiO₂ compared to 74% with NGC adsorbent. The percentage removal of 4-NP was higher than 3-NP which was also higher than 2,4-DNP using NGC–TiO₂. 4-NP adsorption best fitted to the Langmuir isotherm plot with <i>R</i>² value of 0.9981 and adsorption capacity of 52.91 mg g⁻¹. The adsorption process of NP was found to follow a pseudo-second-order kinetic model. The rate constant value for the adsorption of 10⁻⁴ M 4-NP at pH 3 using 10 mg of NGC–TiO₂ adsorbent was found to be 3.76 × 10⁻⁵ g.mg⁻¹.min⁻¹