Concepedia

Enantioselective Synthesis of Nonracemic Geminal Silylboronates by Pt-Catalyzed Hydrosilylation

Adam A. Szymaniak, Chenlong Zhang, John R. Coombs, James P. Morken

ACS Catalysis · 2018 · 76 citations · 39 references

DOI

Concepts

Abstract

A Pt-catalyzed enantioselective hydrosilylation of alkenylboronates is described. This reaction occurs with high regio- and enantioselectivity, providing a convenient route to chiral non-racemic geminal silylboronates. These compounds are useful reagents in stereoselective synthesis.

References

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