Concepedia

Engaging sulfinate salts <i>via</i> Ni/photoredox dual catalysis enables facile C<sub>sp2</sub>–SO<sub>2</sub>R coupling

María Jesús Cabrera‐Afonso, Zhipeng Lu, Christopher B. Kelly, Simon B. Lang, Ryan Dykstra, Osvaldo Gutiérrez, Gary A. Molander

Chemical Science · 2018 · 134 citations · 34 references

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Concepts

Abstract

cross-coupling, an array of diverse sulfone scaffolds can be readily assembled from bifunctional electrophiles. A mechanistic manifold consistent with experimental and computational data is presented.

References

34

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John F. Hartwig · Accounts of Chemical Research · 2008 · 1.9K citations · Full text

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Merging photoredox with nickel catalysis: Coupling of α-carboxyl sp <sup>3</sup> -carbons with aryl halides

Zhiwei Zuo, Derek T. Ahneman, Lingling Chu et al. · Science · 2014 · 1.6K citations · Full text

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Single-electron transmetalation in organoboron cross-coupling by photoredox/nickel dual catalysis

John C. Tellis, David N. Primer, Gary A. Molander · Science · 2014 · 1.3K citations · Full text

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Single-Electron Transmetalation via Photoredox/Nickel Dual Catalysis: Unlocking a New Paradigm for sp<sup>3</sup>–sp<sup>2</sup> Cross-Coupling

John C. Tellis, Christopher B. Kelly, David N. Primer et al. · Accounts of Chemical Research · 2016 · 687 citations · Full text

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Nickel-Catalyzed Cross-Coupling of Photoredox-Generated Radicals: Uncovering a General Manifold for Stereoconvergence in Nickel-Catalyzed Cross-Couplings

Osvaldo Gutiérrez, John C. Tellis, David N. Primer et al. · Journal of the American Chemical Society · 2015 · 604 citations · Full text

, , +14