Rational Synthesis and Assembly of Ni₃S₄ Nanorods for Enhanced Electrochemical Sodium-Ion Storage

Abstract

Even though advocated as the potential low-cost alternatives to current lithium-ion technology, the practical viability of sodium-ion batteries remains illusive and depends on the development of high-performance electrode materials. Very few candidates available at present can simultaneously meet the requirements on capacity, rate capability, and cycle life. Herein, we report a high-temperature solution method to prepare Ni₃S₄ nanorods with uniform sizes. These colloidal nanorods readily self-assemble side by side and form microsized superstructures, which unfortunately negates the nanoscale feature of individual nanorods. To this end, we further introduce two-dimensional graphene nanosheets as the spacer to interrupt nanorod self-assembly. Resultant composite presents a marked advantage toward electrochemical storage of Na⁺ ions. We demonstrate that in half-cells it exhibits large reversible specific capacity in excess of 600 mAh/g, high rate capability with >300 mAh/g retained at 4 A/g, and great cycle life at different current rates. This anode material can also be combined with the NASICON-type Na₃V₂(PO₄)₃ cathode in full cells to enable large capacity and good cyclability.