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Synthesis of chiral γ-aminophosphonates through the organocatalytic hydrophosphonylation of azadienes with phosphites
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Citations
32
References
2018
Year
Novel OrganocatalystsEngineeringOrganocatalytic HydrophosphonylationFacile RouteOrganic ChemistryCatalysisStereoselective SynthesisChemistryChiral γ-AminophosphonatesAsymmetric CatalysisActive γ-AminophosphonatesSynthetic ChemistryEnantioselective SynthesisBiomolecular EngineeringOrganocatalytic Enantioselective 1,4-Addition
An organocatalytic enantioselective 1,4-addition of phosphites to azadienes has been successfully developed using quinine as a catalyst, providing an efficient and facile route to optically active γ-aminophosphonates with up to 94% ee.
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