Publication | Closed Access
Visible‐Light‐Promoted Synthesis of 1,4‐Dicarbonyl Compounds via Conjugate Addition of Aroyl Chlorides
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Citations
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References
2018
Year
Chemical EngineeringAvailable Aroyl ChloridesEngineeringPhotoredox ProcessPhotochemistryNovel OrganocatalystsSynthetic PhotochemistryOrganic ChemistryPhotocatalysisCatalysisChemistryHeterocycle ChemistryConjugate AdditionSynthetic ChemistryAryl Radical SourcesAroyl ChloridesMichael Acceptors
A facile visible-light photocatalytic conjugate addition to prepare 1,4-dicarbonyl compounds has been developed by employing readily available aroyl chlorides as aryl radical sources. This operationally simple method shows a broad scope with regard to both aroyl chlorides and Michael acceptors. As a result, a variety of 1,4-diketones were efficiently synthesized in moderate to good yields.
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