Why Does CuFeS₂ Resemble Gold?

Abstract

While several potential applications of CuFeS₂ quantum dots have already been reported, doubts regarding their optical and physical properties persist. In particular, it is unclear if the quantum dot material is metallic, a degenerately doped semiconductor, or else an intrinsic semiconductor material. Here we examine the physical properties of CuFeS₂ quantum dots in order to address this issue. Specifically, we study the bump that is observed in the optical spectra of these quantum dots at ∼500 nm. Using a combination of structural and optical characterization methods, ultrafast spectroscopy, as well as electronic structure calculations, we ascertain that the unusual purple color of CuFeS₂ quantum dots as well the golden luster of CuFeS₂ films arise from the existence of a plasmon resonance in these materials. While the presence of free carriers causes this material to resemble gold, surface treatments are also described to suppress the plasmon resonance altogether.