Science · 2018 · 294 citations · 75 references
Natural SciencesChemistryMaterials ScienceNanomaterialsNanotechnologyOptical MaterialsInorganic NanoparticlesMagnetic NanomaterialsMagnetic OxidesMagnetic Properties Of SolidsMagnetism In SolidsMagnetism Of Inorganic CompoundsChiral OpticsChirality In GelsCircular DichroismNanoparticlesNanostructuresOptical ActivityTransition Dipole MomentsTransition Metal Oxides
nanoparticles with chiral distortions of the crystal lattices exhibited chiroptical activity in the visible range that was 10 times as strong as that of nonparamagnetic nanoparticles of comparable size. Transparency of the nanoparticle gels to circularly polarized light beams in the ultraviolet range was reversibly modulated by magnetic fields. These phenomena were also observed for other nanoscale metal oxides with lattice distortions from imprinted amino acids and other chiral ligands. The large family of chiral ceramic nanostructures and gels can be pivotal for new technologies and knowledge at the nexus of chirality and magnetism.
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Density-functional thermochemistry. III. The role of exact exchange
Axel D. Becke · The Journal of Chemical Physics · 1993 · 102.8K citations
Natural Sciences, Chemistry, Physics +13
Frank Neese · Wiley Interdisciplinary Reviews Computational Molecular Science · 2011 · 13.1K citations
Natural Sciences, Chemistry, Physics +17