Critical Reviews in Environmental Science and Technology · 2017 · 299 citations · 135 references
Natural SciencesChemical EngineeringEnvironmental EngineeringElectrochemistryWastewater TreatmentWater TreatmentElectrochemical KineticsElectrode KineticsElectrode MaterialsRedox ChemistryRedox ProcessesRedox ReactionsCurrent DensityElectrochemical OxidationFenton ReactionMechanistic Kinetic ModelingOxidation ProcessesWastewater Treatment By ElectrochemistryWastewater Treatment PlantsWastewater Treatment Processes
Electro-Fenton process is an emerging treatment technology for water and wastewater treatment. Electro-Fenton utilizes hydroxyl radicals to oxidize hazardous contaminants and is especially useful to treat recalcitrant compounds that are not easily degraded in conventional water and wastewater treatment plants. This paper reviews the mechanism of electro-Fenton process and its kinetic modeling. The effects of electrode materials, hydrogen peroxide concentration, ferrous ion concentration, pH, electrolyte, oxygen sparging rate, temperature, initial concentration of pollutant, feeding mode, current density, and distance between electrodes are also reviewed. The performance of electro-Fenton is compared with other treatment technologies. Finally, existing challenges and future perspectives are discussed.
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George V. Buxton, C.L. Greenstock, W. Phillips Helman et al. · Journal of Physical and Chemical Reference Data · 1988 · 12.1K citations