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Enantioselective Conjugate Addition of 2‐Acylimidazoles with Nitroalkenes Promoted by Chiral‐at‐Metal Rhodium(III) Complexes
17
Citations
60
References
2017
Year
Chiral‐at‐metal RhodiumInorganic ChemistryEngineeringEnantioselective Conjugate AdditionOrganic ChemistryOrganometallic CatalysisCatalysisChemistryAsymmetric CatalysisSynthetic ChemistryEnantioselective SynthesisBiomolecular EngineeringGood YieldsMild Reaction Conditions
Abstract An enantioselective conjugate addition of 2‐acylimidazoles with nitroalkenes catalyzed by chiral‐at‐metal rhodium(III) complex under mild reaction conditions was developed, affording versatile γ ‐nitro ketone skeletons in good yields with excellent enantioselectivities (up to >99% ee). magnified image
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