Molecular Design of Efficient Organic D–A––A Dye Featuring Triphenylamine as Donor Fragment for Application in Dye‐Sensitized Solar Cells

Abstract

A metal-free organic sensitizer, suitable for the application in dye-sensitized solar cells (DSSCs), has been designed, synthesized and characterized both experimentally and theoretically. The structure of the novel donor-acceptor-π-bridge-acceptor (D-A-π-A) dye incorporates a triphenylamine (TPA) segment and 4-(benzo[c][1,2,5]thiadiazol-4-ylethynyl)benzoic acid (BTEBA). The triphenylamine unit is widely used as an electron donor for photosensitizers, owing to its nonplanar molecular configuration and excellent electron-donating capability, whereas 4-(benzo[c][1,2,5]thiadiazol-4-ylethynyl)benzoic acid is used as an electron acceptor unit. The influences of I₃^- /I^- , [Co(bpy)₃ ]^3+/2+ and [Cu(tmby)₂ ]^2+/+ (tmby=4,4',6,6'-tetramethyl-2,2'-bipyridine) as redox electrolytes on the DSSC device performance were also investigated. The maximal monochromatic incident photon-to-current conversion efficiency (IPCE) reached 81 % and the solar light to electrical energy conversion efficiency of devices with [Cu(tmby)₂ ]^2+/+ reached 7.15 %. The devices with [Co(bpy)₃ ]^3+/2+ and I₃^- /I^- electrolytes gave efficiencies of 5.22 % and 6.14 %, respectively. The lowest device performance with a [Co(bpy)₃ ]^3+/2+ -based electrolyte is attributed to increased charge recombination.