[Ag₁₅(N-triphos)₄(Cl₄)](NO₃)₃: a stable Ag–P superatom with eight electrons (N-triphos = tris((diphenylphosphino)methyl)amine)

Abstract

) are in the range of 2.57-2.71 Å, and the distances between the face-capped and the vertical silver atoms are in the range of 2.84-2.92 Å, showing strong AgAg interactions within this cluster core. This superatom complex exhibits a relatively high thermal and photolytic stability.