Coherently aligned nanoparticles within a biogenic single crystal: A biological prestressing strategy

Iryna Polishchuk, Avigail Aronhime Bracha, Leonid Bloch, Davide Levy, Stas Kozachkevich, Yael Etinger-Geller, Yaron Kauffmann, Manfred Burghammer, Carlotta Giacobbe, Julie Villanova,

Science · 2017 · 143 citations · 49 references

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Abstract

Many roads to being tough A number of routes exist to increase toughness in both natural and human-made materials—for example, using secondary phases and precipitates or exploiting tailored architectures and shaped crystals. Polishchuk et al. detail the nanoscale internal structure of calcitic microlenses formed by a brittlestar (see the Perspective by Duffy). The segregation of magnesium-rich particles forms a secondary phase that places compressive stresses on the host matrix. This toughening mechanism resembles Guinier-Preston zones known in classical metallurgy. Science , this issue p. 1294 see also p. 1254

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