Concepedia

Practical synthesis of enantiopure benzylamines by catalytic hydrogenation or transfer hydrogenation reactions in isopropanol using a Ru-pybox catalyst

Eire De Julián, Estefanía Menéndez‐Pedregal, Miguel Claros, Mónica Vaquero, Elena Lastra, Pilar Gamasa, Antonio Pizzano

Organic Chemistry Frontiers · 2017 · 14 citations · 58 references

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Concepts

Abstract

A Ru/Ph-pybox catalyst provides a very high enantioselectivity in the hydrogenation and transfer hydrogenation of <italic>N</italic>-aryl imines.

References

58

Industrial Methods for the Production of Optically Active Intermediates

Michael Breuer, Klaus Ditrich, Tilo Habicher et al. · Angewandte Chemie International Edition · 2004 · 1.4K citations · Full text

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Mechanisms of the H2-hydrogenation and transfer hydrogenation of polar bonds catalyzed by ruthenium hydride complexes

S.E. Clapham, A. Hadzovic, Robert H. Morris · Coordination Chemistry Reviews · 2004 · 1.3K citations

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Chiral Amine Synthesis – Recent Developments and Trends for Enamide Reduction, Reductive Amination, and Imine Reduction

Thomas C. Nugent, Mohamed El‐Shazly · Advanced Synthesis & Catalysis · 2010 · 887 citations

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Asymmetric Transfer Hydrogenation of Imines

Nobuyuki Uematsu, Akio Fujii, Shohei Hashiguchi et al. · Journal of the American Chemical Society · 1996 · 816 citations

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Amine(imine)diphosphine Iron Catalysts for Asymmetric Transfer Hydrogenation of Ketones and Imines

Weiwei Zuo, Alan J. Lough, Young Feng Li et al. · Science · 2013 · 509 citations · Full text

, , +17