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Construction of luminescent high-nuclearity Zn–Ln rectangular nanoclusters with flexible long-chain Schiff base ligands

DOI

28

Citations

40

References

2017

Year

Shi‐Qing Wang, Xiaoping Yang, Ting Zhu, Le Bo, Ruihu Wang, Shaoming Huang, Chengri Wang, Dongmei Jiang, Hongfen Chen, Richard A. Jones
Dalton Transactions

Abstract

Three Zn-Ln clusters [Ln<sub>8</sub>Zn<sub>6</sub>(L<sup>1</sup>)<sub>2</sub>(OAc)<sub>20</sub>(O)<sub>2</sub>(NO<sub>3</sub>)<sub>4</sub>(OH)<sub>4</sub>] (Ln = Sm (1) and Nd (2)) and [Nd<sub>4</sub>Zn<sub>4</sub>(L<sup>2</sup>)<sub>2</sub>(OAc)<sub>10</sub>(NO<sub>3</sub>)<sub>2</sub>(OH)<sub>4</sub>] (3) were prepared using two long-chain Schiff base ligands. The Zn-Ln clusters exhibit interesting nano-square-like structures. Their visible and NIR luminescence properties were investigated.

References

YearCitations

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