Models for aerobic carbon monoxide dehydrogenase: synthesis, characterization and reactivity of paramagnetic Mo^VO(μ-S)Cu^I complexes

Abstract

), supporting the hypothesis that the electronic structure of the MoO(μ-S)Cu core unit and the degree of intermetallic communication are strongly dependent on the geometry of the MoO(OR)(μ-S)Cu unit. The complexes participate in an electrochemically reversible Mo(vi)/Mo(v) redox couple and react with cyanide undergoing decupration and desulfurization reactions of the type observed for CODH.