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Strategies for the Construction of Supramolecular Dimers versus Homoleptic 1D Coordination Polymers Starting from the Diphosphorus [Cp<sub>2</sub>Mo<sub>2</sub>(CO)<sub>4</sub>(η<sup>2</sup>‐P<sub>2</sub>)] Complex and Silver(I) Salts

DOIFull Paper Access

29

Citations

28

References

2017

Year

Mehdi Elsayed Moussa, M. Fleischmann, Eugenia V. Peresypkina, Luis Dütsch, Michael Seidl, Gábor Balázs, Manfred Scheer
European Journal of Inorganic Chemistry

Abstract

The reactions of the tetrahedral diphosphorus [Cp<sub>2</sub>Mo<sub>2</sub>(CO)<sub>4</sub>(η<sup>2</sup>-P<sub>2</sub>)] (<b>1</b>; Cp = C<sub>5</sub>H<sub>5</sub>) complex with Ag[Al{OC(CF<sub>3</sub>)<sub>3</sub>}<sub>4</sub>] (AgTEF) (<b>A</b>) and Ag[FAl{OC(C<sub>6</sub>F<sub>5</sub>)(C<sub>6</sub>F<sub>10</sub>)}<sub>3</sub>] (AgFAl) (<b>B</b>) were studied. The first reaction led to the formation of the [Ag<sub>2</sub>(η<sup>2</sup>-<b>1</b>)<sub>2</sub>(η<sup>1</sup>:η<sup>1</sup>-<b>1</b>)<sub>2</sub>][TEF]<sub>2</sub> (<b>2</b>) dimer and the [Ag<sub>2</sub>(η<sup>1</sup>:η<sup>1</sup>-<b>1</b>)<sub>3</sub>] <i><sub>n</sub></i> [TEF]<sub>2<i>n</i></sub> (<b>3</b>) coordination polymer, whereas the second reaction afforded the [Ag<sub>2</sub>(η<sup>1</sup>:η<sup>1</sup>-<b>1</b>)<sub>2</sub>(η<sup>1</sup>-CH<sub>2</sub>Cl<sub>2</sub>)<sub>2</sub>(η<sup>2</sup>-C<sub>7</sub>H<sub>8</sub>)<sub>2</sub>][FAl]<sub>2</sub> (<b>4</b>) or the [Ag<sub>2</sub>(η<sup>2</sup>-<b>1</b>)<sub>2</sub>(η<sup>1</sup>:η<sup>1</sup>-<b>1</b>)<sub>2</sub>][FAl]<sub>2</sub> (<b>5</b>) dimer and the [Ag<sub>2</sub>(η<sup>1</sup>:η<sup>1</sup>-<b>1</b>)<sub>4</sub>] <i><sub>n</sub></i> [FAl]<sub>2<i>n</i></sub> (<b>6</b>) coordination polymer. In each case, the products obtained depended on the ratio of the reactants and/or the synthetic procedure.

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