Photodissociation dynamics of fulvenallene and the fulvenallenyl radical at 248 and 193 nm

Isaac A. Ramphal, Mark Shapero, Courtney Haibach-Morris, Daniel M. Neumark

Physical Chemistry Chemical Physics · 2017 · 13 citations · 47 references

Concepts

Abstract

Photofragment translational spectroscopy was used to study the photodissociation of fulvenallene, C<sub>7</sub>H<sub>6</sub>, and the fulvenallenyl radical, C<sub>7</sub>H<sub>5</sub>. Fulvenallene only loses H atoms to form fulvenallenyl. Fulvenallenyl exhibits both C<sub>2</sub>H<sub>2</sub>-loss and C<sub>3</sub>H<sub>3</sub>-loss pathways.

References

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