Microscopic origin of the mobility enhancement at a spinel/perovskite oxide heterointerface revealed by photoemission spectroscopy

Abstract

The spinel/perovskite heterointerface $\ensuremath{\gamma}\ensuremath{-}{\mathrm{Al}}_{2}{\mathrm{O}}_{3}/{\mathrm{SrTiO}}_{3}$ hosts a two-dimensional electron system (2DES) with electron mobilities exceeding those in its all-perovskite counterpart ${\mathrm{LaAlO}}_{3}/{\mathrm{SrTiO}}_{3}$ by more than an order of magnitude, despite the abundance of oxygen vacancies which act as electron donors as well as scattering sites. By means of resonant soft x-ray photoemission spectroscopy and ab initio calculations, we reveal the presence of a sharply localized type of oxygen vacancies at the very interface due to the local breaking of the perovskite symmetry. We explain the extraordinarily high mobilities by reduced scattering resulting from the preferential formation of interfacial oxygen vacancies and spatial separation of the resulting 2DES in deeper ${\mathrm{SrTiO}}_{3}$ layers. Our findings comply with transport studies and pave the way towards defect engineering at interfaces of oxides with different crystal structures.