Magnetomigration of Rare-Earth Ions Triggered by Concentration Gradients

Abstract

Mach-Zehnder interferometry was applied to explore the effects of inhomogeneous magnetic fields on the mobility of rare-earth ions in aqueous solutions. No migration of ions was observed in a thermodynamically closed system when a homogeneous solution was subjected to a magnetic field gradient alone. However, magnetomigration could be triggered by a concentration gradient of the rare-earth ions in the solution. When a concentration gradient was introduced in the sample by solvent evaporation, consistent migration of paramagnetic Dy³⁺ ions from the bulk solution to regions with stronger magnetic fields was observed. By contrast, no movement was detected for diamagnetic Y³⁺ ions in the presence of a concentration gradient.