Concepedia

A matrix of heterobimetallic complexes for interrogation of hydrogen evolution reaction electrocatalysts

Pokhraj Ghosh, Shengda Ding, Rachel B. Chupik, Manuel Quiroz, Chung‐Hung Hsieh, N.S.P. Bhuvanesh, Michael B. Hall, Marcetta Y. Darensbourg

Chemical Science · 2017 · 61 citations · 42 references

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Concepts

Abstract

Nitrosyls as electron reservoirs guide protons to favorable sites in bimetallic HER catalysts.

References

42

Principles of structure, bonding, and reactivity for metal nitrosyl complexes

John H. Enemark, Robert D. Feltham · Coordination Chemistry Reviews · 1974 · 1.6K citations

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A Synthetic Nickel Electrocatalyst with a Turnover Frequency Above 100,000 s <sup>−1</sup> for H <sub>2</sub> Production

Monte L. Helm, Michael Stewart, R. Morris Bullock et al. · Science · 2011 · 1.2K citations · Full text

, , +17

Biomimetic assembly and activation of [FeFe]-hydrogenases

Gustav Berggren, Agnieszka Adamska, Camilla Lambertz et al. · Nature · 2013 · 689 citations · Full text

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H<sub>2</sub> Evolution and Molecular Electrocatalysts: Determination of Overpotentials and Effect of Homoconjugation

Vincent Fourmond, Pierre-André Jacques, Marc Fontecave et al. · Inorganic Chemistry · 2010 · 474 citations

, , +17

Iron-Only Hydrogenase Mimics. Thermodynamic Aspects of the Use of Electrochemistry to Evaluate Catalytic Efficiency for Hydrogen Generation

Greg A. N. Felton, Richard S. Glass, Dennis L. Lichtenberger et al. · Inorganic Chemistry · 2006 · 473 citations

, , +16