Concepedia

Synthesis and derivatisation of ceric tris(tert-butoxy)siloxides

Jochen Friedrich, Cäcilia Maichle‐Mößmer, Reiner Anwander

Chemical Communications · 2017 · 20 citations · 60 references

DOI

Concepts

Abstract

Heteroleptic ceric Ce[OSi(O<italic>t</italic>Bu)<sub>3</sub>]<sub>3</sub>Cl(thf) is straightforwardly obtained from cerous Ce[OSi(O<italic>t</italic>Bu)<sub>3</sub>]<sub>3</sub>(thf)<sub>2</sub>and trityl chloride and gives access to the terminal siloxy/methoxy derivative Ce[OSi(O<italic>t</italic>Bu)<sub>3</sub>]<sub>3</sub>(OCH<sub>3</sub>)(thf)<sub>2</sub>.

References

60

Low co-ordination numbers in lanthanide and actinide compounds. Part I. The preparation and characterization of tris{bis(trimethylsilyl)-amido}lanthanides

D. C. Bradley, Joginder S. Ghotra, F. A. Hart · Journal of the Chemical Society Dalton Transactions · 1973 · 447 citations

, , +17

The electrochemical behavior of cerium(III/IV) complexes: Thermodynamics, kinetics and applications in synthesis

Nicholas A. Piro, Jerome R. Robinson, Patrick J. Walsh et al. · Coordination Chemistry Reviews · 2013 · 239 citations

, , +12

Stereospecific Polymerization of Isoprene with Molecular and MCM‐48‐Grafted Lanthanide(<scp>III</scp>) Tetraalkylaluminates

Andreas Fischbach, Michael G. Klimpel, Markus Widenmeyer et al. · Angewandte Chemie International Edition · 2004 · 188 citations

, , +14

Chemistry of electrophilic metal centres coordinated by silox ( Bu3SiO), tritox ( Bu3CO) and related binfunctional ligands

Peter T. Wolczanski · Polyhedron · 1995 · 185 citations · Full text

, , +12

Tuning Uranium–Nitrogen Multiple Bond Formation with Ancillary Siloxide Ligands

Clément Camp, Jacques Pécaut, Marinella Mazzanti · Journal of the American Chemical Society · 2013 · 157 citations · Full text

, , +15