Concepedia

Ruthenium(<scp>ii</scp>) complexes of pyridinol and N-heterocyclic carbene derived pincers as robust catalysts for selective carbon dioxide reduction

Chance M. Boudreaux, Nalaka P. Liyanage, Hunter Shirley, Sopheavy Siek, Deidra L. Gerlach, Fengrui Qu, Jared H. Delcamp, Elizabeth T. Papish

Chemical Communications · 2017 · 54 citations · 40 references

DOI

Concepts

Abstract

reduction. The methoxy group on the pyridine ring offers unique catalysis advantages not seen with the unsubstituted analog. Our best catalyst offers selective CO formation, ∼250 turnover cycles, and a 40 h lifetime.

References

40

Looking for Stable Carbenes:  The Difficulty in Starting Anew

Anthony J. Arduengo · Accounts of Chemical Research · 1999 · 1.2K citations

, , +5

Reversible hydrogen storage using CO2 and a proton-switchable iridium catalyst in aqueous media under mild temperatures and pressures

Jonathan F. Hull, Yuichiro Himeda, Wan‐Hui Wang et al. · Nature Chemistry · 2012 · 932 citations

, , +14

Selective CO<sub>2</sub> Conversion to Formate Conjugated with H<sub>2</sub>O Oxidation Utilizing Semiconductor/Complex Hybrid Photocatalysts

Shunsuke Sato, Takeo Arai, Takeshi Morikawa et al. · Journal of the American Chemical Society · 2011 · 495 citations

, , +17

Visible-Light Photoredox Catalysis: Selective Reduction of Carbon Dioxide to Carbon Monoxide by a Nickel <i>N</i>-Heterocyclic Carbene–Isoquinoline Complex

V. Sara Thoi, Nikolay Kornienko, Charles G. Margarit et al. · Journal of the American Chemical Society · 2013 · 367 citations · Full text

, , +17

Photocatalytic CO <sub>2</sub> reduction with high turnover frequency and selectivity of formic acid formation using Ru(II) multinuclear complexes

Yusuke Tamaki, Tatsuki Morimoto, Kazuhide Koike et al. · Proceedings of the National Academy of Sciences · 2012 · 338 citations · Full text

, , +17