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Preorganized Ag<sup>I</sup> Bimetallic Precursor with Labile Diphosphorus Ligands for a Programmed Synthesis of Organometallic–Organic Hybrid Polymers

DOIFull Paper Access

19

Citations

60

References

2017

Year

Mehdi Elsayed Moussa, Michael Seidl, Gábor Balázs, Manfred Zabel, A.V. Virovets, Bianca Attenberger, Andrea Schreiner, Manfred Scheer
Chemistry - A European Journal

Abstract

An Ag<sup>I</sup> dimer capped with labile organometallic diphosphorus ligands [Cp<sub>2</sub> Mo<sub>2</sub> (CO)<sub>4</sub> (η<sup>2</sup> -P<sub>2</sub> )] (Cp=C<sub>5</sub> H<sub>5</sub> ) acts as a highly pre-organized molecular precursor to direct the construction of 1D or 2D, and 3D organometallic-organic hybrid coordination polymers upon reaction with ditopic pyridine-based linkers. The formation of the supramolecular aggregates can be controlled by the stoichiometry of the organic molecules, and the mechanism is supported by DFT calculations.

References

YearCitations

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