Publication | Open Access
Biocatalytic synthesis of chiral cyclic γ-oxoesters by sequential C–H hydroxylation, alcohol oxidation and alkene reduction
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Citations
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References
2017
Year
Biocatalytic SynthesisRoom TemperatureChemical EngineeringEngineeringBiochemistryEnvironmentally-unfriendly OxidantsNatural SciencesChiral Cyclic γ-OxoestersOrganic ChemistryCatalysisStereoselective SynthesisChemistryAlcohol OxidationAsymmetric CatalysisCorresponding Cyclic γ-OxoestersEnantioselective SynthesisCatalytic Synthesis
The conversion of C<sub>5</sub> and C<sub>6</sub> cycloalkenecarboxylates into both enantiomers of the corresponding cyclic γ-oxoesters is performed at room temperature using three enzymes and no environmentally-unfriendly oxidants.
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