Synthesis, Structure and Reactivity of a Borylene Cation [(NHSi)₂B(CO)]⁺ Stabilized by Three Neutral Ligands

Abstract

A borylene cation stabilized by bis(silylene) and carbon monoxide was prepared and structurally characterized via the reaction of bis(silylene)-stabilized bromoborylene with W(CO)₆. This is the first example of a borylene cation coordinated by three neutral ligands, which can be viewed as a cationic form of a long-sought Lewis base-stabilized zerovalent boron compound. This cation can cleave dihydrogen.