(C₆H₅C₂H₄NH₃)₂GeI₄: A Layered Two-Dimensional Perovskite with Potential for Photovoltaic Applications

Abstract

Recently, two-dimensional organic-inorganic perovskites have attracted increasing attention due to their unique photophysical properties and high stability. Here we report a lead-free, two-dimensional perovskite, (PEA)₂GeI₄ (PEA = C₆H₅(CH₂)₂NH₃⁺). Structural characterization demonstrated that this 2D perovskite structure is formed with inorganic germanium iodide planes separated by organic PEAI layers. (PEA)₂GeI₄ has a direct band gap of 2.12 eV, in agreement with 2.17 eV obtained by density functional theory (DFT) calculations, implying that it is suitable for a tandem solar cell. (PEA)₂GeI₄ luminesces at room-temperature with a moderate lifetime, exhibiting good potential for photovoltaic applications. In addition, 2D (PEA)₂GeI₄ is more stable than 3D CH₃NH₃GeI₃ in air, owing to the presence of a hydrophobic organic long chain. This work provides a direction for the development of 2D Ge-based perovskites with potential for photovoltaic applications.