Oxidative addition/cycloaddition of arenesulfonamides and triflamide to N-allyltriflamide and N,N-diallyltriflamide

Abstract

Mono- and diallyltriflamides react with triflamide in the oxidative system <italic>t</italic>-BuOCl + NaI to give the products of addition and cycloaddition, unlike the reaction of <italic>N</italic>-allyltriflamide with arenesulfonamides or trifluoroacetamide leading to chlorination and cyclodimerization.