Chemical Communications · 2017 · 65 citations · 39 references
Natural SciencesChemical EngineeringChemistryCatalysisElectrochemistryInorganic ChemistryCoordination ChemistryElectrochemical Energy ConversionElectrode KineticsMetal Ion CatalysisMetal-ligand BondingNanocatalysisCobalt CatalysisNickel CatalysisOxidation - Reduction PotentialOxidation-reduction PotentialPincer Complexes
) reported. Rates improved in the presence of water and, significantly, catalysis occurred at the first reduction potential, presumably at the Ni(i) state. Controlled potential electrolysis (CPE) was found to yield CO at 34% and formate at 47% Faradaic efficiency (FE).
39