Enhanced Second-Harmonic Generation from Sequential Capillarity-Assisted Particle Assembly of Hybrid Nanodimers

Abstract

We show enhanced second-harmonic generation (SHG) from a hybrid metal-dielectric nanodimer consisting of an inorganic perovskite nanoparticle of barium titanate (BaTiO₃) coupled to a metallic gold (Au) nanoparticle. BaTiO₃-Au nanodimers of 100 nm/80 nm sizes are fabricated by sequential capillarity-assisted particle assembly. The BaTiO₃ nanoparticle has a noncentrosymmetric crystalline structure and generates bulk SHG. We use the localized surface plasmon resonance of the gold nanoparticle to enhance the SHG from the BaTiO₃ nanoparticle. We experimentally measure the nonlinear signal from assembled nanodimers and demonstrate an up to 15-fold enhancement compared to a single BaTiO₃ nanoparticle. We further perform numerical simulations of the linear and SHG spectra of the BaTiO₃-Au nanodimer and show that the gold nanoparticle acts as a nanoantenna at the SHG wavelength.