Concepedia

The amorphous state: first-principles derivation of the Gordon–Taylor equation for direct prediction of the glass transition temperature of mixtures; estimation of the crossover temperature of fragile glass formers; physical basis of the “Rule of 2/3”

Peter J. Skrdla, Philip D. Floyd, Philip C. Dell’Orco

Physical Chemistry Chemical Physics · 2017 · 42 citations · 37 references

DOI

Concepts

Abstract

, of the corresponding crystalline phase, is shown to be underpinned by the heat capacity ratio of the two phases referenced to a common temperature, as evidenced by the calculations put forth for indomethacin and felodipine.

References

37

Supercooled liquids and the glass transition

Pablo G. Debenedetti, Frank H. Stillinger · Nature · 2001 · 4.6K citations

, , +13

Ideal copolymers and the second‐order transitions of synthetic rubbers. i. non‐crystalline copolymers

M. Gordon, James S. Taylor · Journal of Applied Chemistry · 1952 · 2.6K citations

, , +17

Influence of Diluent and of Copolymer Composition on the Glass Temperature of a Poly-mer System

Thomas Fox · Medical Entomology and Zoology · 1956 · 1.8K citations

, , +16

Viscosity of glass-forming liquids

John C. Mauro, Yuanzheng Yue, Adam J. Ellison et al. · Proceedings of the National Academy of Sciences · 2009 · 988 citations · Full text

, , +14

Molecular Mobility of Amorphous Pharmaceutical Solids Below Their Glass Transition Temperatures

Bruno C. Hancock, Sheri L. Shamblin, George Zografi · Pharmaceutical Research · 1995 · 883 citations

, , +15