Concepedia

New mechanistic insights into intramolecular aromatic ligand hydroxylation and benzyl alcohol oxidation initiated by the well-defined (μ-peroxo)diiron(<scp>iii</scp>) complex

Mio Sekino, Hideki Furutachi, Rina Tojo, Ayumi Hishi, Hanako Kajikawa, Takatoshi Suzuki, Kaito Suzuki, Shuhei Fujinami, Shigehisa Akine, Yoko Sakata,

Chemical Communications · 2017 · 16 citations · 39 references

DOI

Concepts

Abstract

, provides a diiron(iv)-oxo species as an active oxidant which is involved in either aromatic ligand hydroxylation or benzyl alcohol oxidation.

References

39

An Fe <sub>2</sub> <sup>IV</sup> O <sub>2</sub> Diamond Core Structure for the Key Intermediate Q of Methane Monooxygenase

Lijin Shu, Jeremy C. Nesheim, Karl Kauffmann et al. · Science · 1997 · 541 citations

, , +14

Structure of the key species in the enzymatic oxidation of methane to methanol

R. Banerjee, Yegor Proshlyakov, John D. Lipscomb et al. · Nature · 2015 · 293 citations

, , +11

Mechanistic Studies of the Reaction of Reduced Methane Monooxygenase Hydroxylase with Dioxygen and Substrates

Ann M. Valentine, Shannon S. Stahl, Stephen J. Lippard · Journal of the American Chemical Society · 1999 · 248 citations

, , +14

Structure and Mössbauer Spectrum of a (μ-1,2-Peroxo)bis(μ-carboxylato)diiron(III) Model for the Peroxo Intermediate in the Methane Monooxygenase Hydroxylase Reaction Cycle

Kimoon Kim, Stephen J. Lippard · Journal of the American Chemical Society · 1996 · 223 citations

, , +8

<i>cis</i>-μ-1,2-Peroxo Diiron Complex:  Structure and Reversible Oxygenation

Takaharu Ookubo, Hideki Sugimoto, Toshihiko Nagayama et al. · Journal of the American Chemical Society · 1996 · 218 citations

, , +6